|Matters and Properties of Matters|
|Atomic Structure with Examples|
|The Mole Concept with Examples|
|Gases with Examples|
|Chemical Reactions with Examples|
|Nuclear Chemistry (Radioactivity)|
|Acids and Bases|
|Rates of Reactions (Chemical Kinetics)|
|--Factors Affecting Chemical Equilibrium|
|--Chemical Equilibrium Cheat Sheet|
|Exams and Problem Solutions|
Factors Affecting Chemical Equilibrium
Concentration, temperature and pressure effect chemical equilibrium. We explain them in detail one by one. However, we first give you Le Chatelier's principle of equilibrium;
" If one of the factors like temperature , pressure or concentration of system is changed then system react this change to conserve equilibrium."
1. Affect of Concentration on Equilibrium:
Adding or removing matters into reaction effect equilibrium. For example, adding reactants or removing products increase the yield of product. On the contrary, adding products or removing reactants increase yield of reactants. I other words, in first situation equilibrium shifts to the right and in second situation equilibrium shifts to the left. For instance;
H2(g) + I2(g) ↔ 2HI(g)
If we add H2 gas to the container, equilibrium shifts to the right and system decrease the concentration of H2. ( Le Chatelier's principle)
2. Affect of Temperature on Equilibrium:
Heat must be given to system at equilibrium to increase temperature of it. This process gives different results in endothermic and exothermic reactions. For example;
H2(g) + I2(g) ↔ 2HI(g) + Heat
Reaction given above is exothermic. To keep equilibrium temperature must be constant. If heat is given to system, according to Le Chatelier's principle system wants to decrease this temperature and equilibrium shift to the left or right. Equilibrium constant of this reaction;
3. Affect of Pressure on Equilibrium:
To talk about affect of pressure on equilibrium, at least one of the matters must be in gas phase. In other words, in a reaction consisting of liquid, aqueous, or solid there is no affect of pressure on equilibrium of this system.
Example: Three container given below are in equilibrium with given reactions.
If volumes of them decreased from point I to II, find in which container equilibrium shifts to the right.
I. In first container, there is no change in the number of moles. Thus, pressure does not effect this reaction.
II. In second container, there is no change in the total number of moles. But, in this reaction moles of gas in this reaction decreases. So, equilibrium shifts to the right.
III. As you can see from the reaction, number of moles of decreases. Thus equilibrium shifts to the right.